Character Table for Point Group D33d

Character table for the D_33d point group

D33d E 2 C33 2 C33^2 2 C11 2 C33^4 2 C33^5 2 C11^2 2 C33^7 2 C33^8 2 C11^3 2 C33^10 2 C3 2 C11^4 2 C33^13 2 C33^14 2 C11^5 2 C33^16 33 C2' i 2 S66 2 S22 2 S66^5 2 S66^7 2 S22^3 2 S6 2 S66^13 2 S22^5 2 S66^17 2 S66^19 2 S22^7 2 S66^23 2 S66^25 2 S22^9 2 S66^29 2 S66^31 33 sd <R> <p> <—d—> <——f——> <———g———> <————h————> <—————i—————> A1g 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 ... ... ....T ....... ........T ........... ............T A2g 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 -1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 -1.00000 ..T ... ..... ....... ......... ........... ............. E1g 2.00000 1.96386 1.85674 1.68251 1.44747 1.16011 0.83083 0.47152 0.09516 -0.28463 -0.65414 -1.00000 -1.30972 -1.57211 -1.77767 -1.91899 -1.99094 0.00000 2.00000 -1.99094 -1.91899 -1.77767 -1.57211 -1.30972 -1.00000 -0.65414 -0.28463 0.09516 0.47152 0.83083 1.16011 1.44747 1.68251 1.85674 1.96386 0.00000 TT. ... ..TT. ....... ......TT. ........... ..........TT. E2g 2.00000 1.85674 1.44747 0.83083 0.09516 -0.65414 -1.30972 -1.77767 -1.99094 -1.91899 -1.57211 -1.00000 -0.28463 0.47152 1.16011 1.68251 1.96386 0.00000 2.00000 1.96386 1.68251 1.16011 0.47152 -0.28463 -1.00000 -1.57211 -1.91899 -1.99094 -1.77767 -1.30972 -0.65414 0.09516 0.83083 1.44747 1.85674 0.00000 ... ... TT... ....... ....TT... ........... ........TT... E3g 2.00000 1.68251 0.83083 -0.28463 -1.30972 -1.91899 -1.91899 -1.30972 -0.28463 0.83083 1.68251 2.00000 1.68251 0.83083 -0.28463 -1.30972 -1.91899 0.00000 2.00000 -1.91899 -1.30972 -0.28463 0.83083 1.68251 2.00000 1.68251 0.83083 -0.28463 -1.30972 -1.91899 -1.91899 -1.30972 -0.28463 0.83083 1.68251 0.00000 ... ... ..... ....... ..TT..... ........... ......TT..... E4g 2.00000 1.44747 0.09516 -1.30972 -1.99094 -1.57211 -0.28463 1.16011 1.96386 1.68251 0.47152 -1.00000 -1.91899 -1.77767 -0.65414 0.83083 1.85674 0.00000 2.00000 1.85674 0.83083 -0.65414 -1.77767 -1.91899 -1.00000 0.47152 1.68251 1.96386 1.16011 -0.28463 -1.57211 -1.99094 -1.30972 0.09516 1.44747 0.00000 ... ... ..... ....... TT....... ........... ....TT....... E5g 2.00000 1.16011 -0.65414 -1.91899 -1.57211 0.09516 1.68251 1.85674 0.47152 -1.30972 -1.99094 -1.00000 0.83083 1.96386 1.44747 -0.28463 -1.77767 0.00000 2.00000 -1.77767 -0.28463 1.44747 1.96386 0.83083 -1.00000 -1.99094 -1.30972 0.47152 1.85674 1.68251 0.09516 -1.57211 -1.91899 -0.65414 1.16011 0.00000 ... ... ..... ....... ......... ........... ..TT......... E6g 2.00000 0.83083 -1.30972 -1.91899 -0.28463 1.68251 1.68251 -0.28463 -1.91899 -1.30972 0.83083 2.00000 0.83083 -1.30972 -1.91899 -0.28463 1.68251 0.00000 2.00000 1.68251 -0.28463 -1.91899 -1.30972 0.83083 2.00000 0.83083 -1.30972 -1.91899 -0.28463 1.68251 1.68251 -0.28463 -1.91899 -1.30972 0.83083 0.00000 ... ... ..... ....... ......... ........... TT........... E7g 2.00000 0.47152 -1.77767 -1.30972 1.16011 1.85674 -0.28463 -1.99094 -0.65414 1.68251 1.44747 -1.00000 -1.91899 0.09516 1.96386 0.83083 -1.57211 0.00000 2.00000 -1.57211 0.83083 1.96386 0.09516 -1.91899 -1.00000 1.44747 1.68251 -0.65414 -1.99094 -0.28463 1.85674 1.16011 -1.30972 -1.77767 0.47152 0.00000 ... ... ..... ....... ......... ........... ............. E8g 2.00000 0.09516 -1.99094 -0.28463 1.96386 0.47152 -1.91899 -0.65414 1.85674 0.83083 -1.77767 -1.00000 1.68251 1.16011 -1.57211 -1.30972 1.44747 0.00000 2.00000 1.44747 -1.30972 -1.57211 1.16011 1.68251 -1.00000 -1.77767 0.83083 1.85674 -0.65414 -1.91899 0.47152 1.96386 -0.28463 -1.99094 0.09516 0.00000 ... ... ..... ....... ......... ........... ............. E9g 2.00000 -0.28463 -1.91899 0.83083 1.68251 -1.30972 -1.30972 1.68251 0.83083 -1.91899 -0.28463 2.00000 -0.28463 -1.91899 0.83083 1.68251 -1.30972 0.00000 2.00000 -1.30972 1.68251 0.83083 -1.91899 -0.28463 2.00000 -0.28463 -1.91899 0.83083 1.68251 -1.30972 -1.30972 1.68251 0.83083 -1.91899 -0.28463 0.00000 ... ... ..... ....... ......... ........... ............. E10g 2.00000 -0.65414 -1.57211 1.68251 0.47152 -1.99094 0.83083 1.44747 -1.77767 -0.28463 1.96386 -1.00000 -1.30972 1.85674 0.09516 -1.91899 1.16011 0.00000 2.00000 1.16011 -1.91899 0.09516 1.85674 -1.30972 -1.00000 1.96386 -0.28463 -1.77767 1.44747 0.83083 -1.99094 0.47152 1.68251 -1.57211 -0.65414 0.00000 ... ... ..... ....... ......... ........... ............. E11g 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 0.00000 2.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 0.00000 ... ... ..... ....... ......... ........... ............. E12g 2.00000 -1.30972 -0.28463 1.68251 -1.91899 0.83083 0.83083 -1.91899 1.68251 -0.28463 -1.30972 2.00000 -1.30972 -0.28463 1.68251 -1.91899 0.83083 0.00000 2.00000 0.83083 -1.91899 1.68251 -0.28463 -1.30972 2.00000 -1.30972 -0.28463 1.68251 -1.91899 0.83083 0.83083 -1.91899 1.68251 -0.28463 -1.30972 0.00000 ... ... ..... ....... ......... ........... ............. E13g 2.00000 -1.57211 0.47152 0.83083 -1.77767 1.96386 -1.30972 0.09516 1.16011 -1.91899 1.85674 -1.00000 -0.28463 1.44747 -1.99094 1.68251 -0.65414 0.00000 2.00000 -0.65414 1.68251 -1.99094 1.44747 -0.28463 -1.00000 1.85674 -1.91899 1.16011 0.09516 -1.30972 1.96386 -1.77767 0.83083 0.47152 -1.57211 0.00000 ... ... ..... ....... ......... ........... ............. E14g 2.00000 -1.77767 1.16011 -0.28463 -0.65414 1.44747 -1.91899 1.96386 -1.57211 0.83083 0.09516 -1.00000 1.68251 -1.99094 1.85674 -1.30972 0.47152 0.00000 2.00000 0.47152 -1.30972 1.85674 -1.99094 1.68251 -1.00000 0.09516 0.83083 -1.57211 1.96386 -1.91899 1.44747 -0.65414 -0.28463 1.16011 -1.77767 0.00000 ... ... ..... ....... ......... ........... ............. E15g 2.00000 -1.91899 1.68251 -1.30972 0.83083 -0.28463 -0.28463 0.83083 -1.30972 1.68251 -1.91899 2.00000 -1.91899 1.68251 -1.30972 0.83083 -0.28463 0.00000 2.00000 -0.28463 0.83083 -1.30972 1.68251 -1.91899 2.00000 -1.91899 1.68251 -1.30972 0.83083 -0.28463 -0.28463 0.83083 -1.30972 1.68251 -1.91899 0.00000 ... ... ..... ....... ......... ........... ............. E16g 2.00000 -1.99094 1.96386 -1.91899 1.85674 -1.77767 1.68251 -1.57211 1.44747 -1.30972 1.16011 -1.00000 0.83083 -0.65414 0.47152 -0.28463 0.09516 0.00000 2.00000 0.09516 -0.28463 0.47152 -0.65414 0.83083 -1.00000 1.16011 -1.30972 1.44747 -1.57211 1.68251 -1.77767 1.85674 -1.91899 1.96386 -1.99094 0.00000 ... ... ..... ....... ......... ........... ............. A1u 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 ... ... ..... ....... ......... ........... ............. A2u 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 -1.00000 1.00000 ... ..T ..... ......T ......... ..........T ............. E1u 2.00000 1.96386 1.85674 1.68251 1.44747 1.16011 0.83083 0.47152 0.09516 -0.28463 -0.65414 -1.00000 -1.30972 -1.57211 -1.77767 -1.91899 -1.99094 0.00000 -2.00000 1.99094 1.91899 1.77767 1.57211 1.30972 1.00000 0.65414 0.28463 -0.09516 -0.47152 -0.83083 -1.16011 -1.44747 -1.68251 -1.85674 -1.96386 0.00000 ... TT. ..... ....TT. ......... ........TT. ............. E2u 2.00000 1.85674 1.44747 0.83083 0.09516 -0.65414 -1.30972 -1.77767 -1.99094 -1.91899 -1.57211 -1.00000 -0.28463 0.47152 1.16011 1.68251 1.96386 0.00000 -2.00000 -1.96386 -1.68251 -1.16011 -0.47152 0.28463 1.00000 1.57211 1.91899 1.99094 1.77767 1.30972 0.65414 -0.09516 -0.83083 -1.44747 -1.85674 0.00000 ... ... ..... ..TT... ......... ......TT... ............. E3u 2.00000 1.68251 0.83083 -0.28463 -1.30972 -1.91899 -1.91899 -1.30972 -0.28463 0.83083 1.68251 2.00000 1.68251 0.83083 -0.28463 -1.30972 -1.91899 0.00000 -2.00000 1.91899 1.30972 0.28463 -0.83083 -1.68251 -2.00000 -1.68251 -0.83083 0.28463 1.30972 1.91899 1.91899 1.30972 0.28463 -0.83083 -1.68251 0.00000 ... ... ..... TT..... ......... ....TT..... ............. E4u 2.00000 1.44747 0.09516 -1.30972 -1.99094 -1.57211 -0.28463 1.16011 1.96386 1.68251 0.47152 -1.00000 -1.91899 -1.77767 -0.65414 0.83083 1.85674 0.00000 -2.00000 -1.85674 -0.83083 0.65414 1.77767 1.91899 1.00000 -0.47152 -1.68251 -1.96386 -1.16011 0.28463 1.57211 1.99094 1.30972 -0.09516 -1.44747 0.00000 ... ... ..... ....... ......... ..TT....... ............. E5u 2.00000 1.16011 -0.65414 -1.91899 -1.57211 0.09516 1.68251 1.85674 0.47152 -1.30972 -1.99094 -1.00000 0.83083 1.96386 1.44747 -0.28463 -1.77767 0.00000 -2.00000 1.77767 0.28463 -1.44747 -1.96386 -0.83083 1.00000 1.99094 1.30972 -0.47152 -1.85674 -1.68251 -0.09516 1.57211 1.91899 0.65414 -1.16011 0.00000 ... ... ..... ....... ......... TT......... ............. E6u 2.00000 0.83083 -1.30972 -1.91899 -0.28463 1.68251 1.68251 -0.28463 -1.91899 -1.30972 0.83083 2.00000 0.83083 -1.30972 -1.91899 -0.28463 1.68251 0.00000 -2.00000 -1.68251 0.28463 1.91899 1.30972 -0.83083 -2.00000 -0.83083 1.30972 1.91899 0.28463 -1.68251 -1.68251 0.28463 1.91899 1.30972 -0.83083 0.00000 ... ... ..... ....... ......... ........... ............. E7u 2.00000 0.47152 -1.77767 -1.30972 1.16011 1.85674 -0.28463 -1.99094 -0.65414 1.68251 1.44747 -1.00000 -1.91899 0.09516 1.96386 0.83083 -1.57211 0.00000 -2.00000 1.57211 -0.83083 -1.96386 -0.09516 1.91899 1.00000 -1.44747 -1.68251 0.65414 1.99094 0.28463 -1.85674 -1.16011 1.30972 1.77767 -0.47152 0.00000 ... ... ..... ....... ......... ........... ............. E8u 2.00000 0.09516 -1.99094 -0.28463 1.96386 0.47152 -1.91899 -0.65414 1.85674 0.83083 -1.77767 -1.00000 1.68251 1.16011 -1.57211 -1.30972 1.44747 0.00000 -2.00000 -1.44747 1.30972 1.57211 -1.16011 -1.68251 1.00000 1.77767 -0.83083 -1.85674 0.65414 1.91899 -0.47152 -1.96386 0.28463 1.99094 -0.09516 0.00000 ... ... ..... ....... ......... ........... ............. E9u 2.00000 -0.28463 -1.91899 0.83083 1.68251 -1.30972 -1.30972 1.68251 0.83083 -1.91899 -0.28463 2.00000 -0.28463 -1.91899 0.83083 1.68251 -1.30972 0.00000 -2.00000 1.30972 -1.68251 -0.83083 1.91899 0.28463 -2.00000 0.28463 1.91899 -0.83083 -1.68251 1.30972 1.30972 -1.68251 -0.83083 1.91899 0.28463 0.00000 ... ... ..... ....... ......... ........... ............. E10u 2.00000 -0.65414 -1.57211 1.68251 0.47152 -1.99094 0.83083 1.44747 -1.77767 -0.28463 1.96386 -1.00000 -1.30972 1.85674 0.09516 -1.91899 1.16011 0.00000 -2.00000 -1.16011 1.91899 -0.09516 -1.85674 1.30972 1.00000 -1.96386 0.28463 1.77767 -1.44747 -0.83083 1.99094 -0.47152 -1.68251 1.57211 0.65414 0.00000 ... ... ..... ....... ......... ........... ............. E11u 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 -1.00000 2.00000 -1.00000 0.00000 -2.00000 1.00000 -2.00000 1.00000 1.00000 -2.00000 1.00000 1.00000 -2.00000 1.00000 1.00000 -2.00000 1.00000 1.00000 -2.00000 1.00000 1.00000 0.00000 ... ... ..... ....... ......... ........... ............. E12u 2.00000 -1.30972 -0.28463 1.68251 -1.91899 0.83083 0.83083 -1.91899 1.68251 -0.28463 -1.30972 2.00000 -1.30972 -0.28463 1.68251 -1.91899 0.83083 0.00000 -2.00000 -0.83083 1.91899 -1.68251 0.28463 1.30972 -2.00000 1.30972 0.28463 -1.68251 1.91899 -0.83083 -0.83083 1.91899 -1.68251 0.28463 1.30972 0.00000 ... ... ..... ....... ......... ........... ............. E13u 2.00000 -1.57211 0.47152 0.83083 -1.77767 1.96386 -1.30972 0.09516 1.16011 -1.91899 1.85674 -1.00000 -0.28463 1.44747 -1.99094 1.68251 -0.65414 0.00000 -2.00000 0.65414 -1.68251 1.99094 -1.44747 0.28463 1.00000 -1.85674 1.91899 -1.16011 -0.09516 1.30972 -1.96386 1.77767 -0.83083 -0.47152 1.57211 0.00000 ... ... ..... ....... ......... ........... ............. E14u 2.00000 -1.77767 1.16011 -0.28463 -0.65414 1.44747 -1.91899 1.96386 -1.57211 0.83083 0.09516 -1.00000 1.68251 -1.99094 1.85674 -1.30972 0.47152 0.00000 -2.00000 -0.47152 1.30972 -1.85674 1.99094 -1.68251 1.00000 -0.09516 -0.83083 1.57211 -1.96386 1.91899 -1.44747 0.65414 0.28463 -1.16011 1.77767 0.00000 ... ... ..... ....... ......... ........... ............. E15u 2.00000 -1.91899 1.68251 -1.30972 0.83083 -0.28463 -0.28463 0.83083 -1.30972 1.68251 -1.91899 2.00000 -1.91899 1.68251 -1.30972 0.83083 -0.28463 0.00000 -2.00000 0.28463 -0.83083 1.30972 -1.68251 1.91899 -2.00000 1.91899 -1.68251 1.30972 -0.83083 0.28463 0.28463 -0.83083 1.30972 -1.68251 1.91899 0.00000 ... ... ..... ....... ......... ........... ............. E16u 2.00000 -1.99094 1.96386 -1.91899 1.85674 -1.77767 1.68251 -1.57211 1.44747 -1.30972 1.16011 -1.00000 0.83083 -0.65414 0.47152 -0.28463 0.09516 0.00000 -2.00000 -0.09516 0.28463 -0.47152 0.65414 -0.83083 1.00000 -1.16011 1.30972 -1.44747 1.57211 -1.68251 1.77767 -1.85674 1.91899 -1.96386 1.99094 0.00000 ... ... ..... ....... ......... ........... ............. Irrational character values: 1.990943845146 = 2*cos(2*π/66) = 2*cos(π/33) 1.963857394525 = 2*cos(4*π/66) = 2*cos(2*π/33) 1.918985947229 = 2*cos(6*π/66) = 2*cos(π/11) 1.856735866032 = 2*cos(8*π/66) = 2*cos(4*π/33) 1.777670897310 = 2*cos(10*π/66) = 2*cos(5*π/33) 1.682507065662 = 2*cos(12*π/66) = 2*cos(2*π/11) 1.572106189486 = 2*cos(14*π/66) = 2*cos(7*π/33) 1.447468076210 = 2*cos(16*π/66) = 2*cos(8*π/33) 1.309721467891 = 2*cos(18*π/66) = 2*cos(3*π/11) 1.160113819142 = 2*cos(20*π/66) = 2*cos(10*π/33) 0.830830026004 = 2*cos(24*π/66) = 2*cos(4*π/11) 0.654135926635 = 2*cos(26*π/66) = 2*cos(13*π/33) 0.471517871019 = 2*cos(28*π/66) = 2*cos(14*π/33) 0.284629676547 = 2*cos(30*π/66) = 2*cos(5*π/11) 0.095163831647 = 2*cos(32*π/66) = 2*cos(16*π/33) Symmetry of Rotations and Cartesian products A1g d+g+i+k+m z², z⁴, z⁶ A2g R R_z E1g R+d+g+i+k+m {R_x, R_y}, {xz, yz}, {xz³, yz³}, {xz⁵, yz⁵} E2g d+g+i+k+m {x²−y², xy}, {z²(x²−y²), xyz²}, {z⁴(x²−y²), xyz⁴} E3g g+i+k+m {xz(x²−3y²), yz(3x²−y²)}, {xz³(x²−3y²), yz³(3x²−y²)} E4g g+i+k+m {(x²−y²)²−4x²y², xy(x²−y²)}, {z²((x²−y²)²−4x²y²), xyz²(x²−y²)} E5g i+k+m {xz(x²−(5+2√5)y²)(x²−(5−2√5)y²), yz((5+2√5)x²−y²)((5−2√5)x²−y²)} E6g i+k+m {x²(x²−3y²)²−y²(3x²−y²)², xy(x²−3y²)(3x²−y²)} E7g k+m E8g k+m E9g m E10g m A2u p+f+h+j+l z, z³, z⁵ E1u p+f+h+j+l {x, y}, {xz², yz²}, {xz⁴, yz⁴} E2u f+h+j+l {z(x²−y²), xyz}, {z³(x²−y²), xyz³} E3u f+h+j+l {x(x²−3y²), y(3x²−y²)}, {xz²(x²−3y²), yz²(3x²−y²)} E4u h+j+l {z((x²−y²)²−4x²y²), xyz(x²−y²)} E5u h+j+l {x(x²−(5+2√5)y²)(x²−(5−2√5)y²), y((5+2√5)x²−y²)((5−2√5)x²−y²)} E6u j+l E7u j+l E8u l E9u l Notes: α The order of the D_33d point group is 132, and the order of the principal axis (S₆₆) is 66. The group has 36 irreducible representations. β The D_33d point group is isomorphic to D_33h, C_66v and D₆₆. γ The D_33d point group is generated by two symmetry elements, S₆₆ and either a perpendicular C₂^′ or a vertical σ_d. Also, the group may be generated from a C₂^′ plus a σ_d (some pairs will yield smaller groups, though; choosing a minimum angle is safe). The canonical choice, however, is to use redundant generators: C₃₃, C₂^′ and i. δ The group contains one set of C₂^′ symmetry axes perpendicular to the principal (z) axis. The x axis (but not the y axis) is a member of that set. Reversely, the single set of symmetry planes denoted σ_d contains the yz plane but not the xz plane. ε The lowest nonvanishing multipole moment in D_33d is 4 (quadrupole moment). ζ This point group is non-Abelian (some symmetry operations are not commutative). Therefore, the character table contains multi-membered classes and degenerate irreducible representations. η Some of the characters in the table are irrational because the order of the principal axis is neither 1,2,3,4 nor 6. These irrational values can be expressed as cosine values, or as solutions of algebraic equations with a leading coefficient of 1. All characters are algebraic integers of a degree much less than half the order of the principal axis. For this group, however, none of the irrational characters can be expressed by a closed algebraic form using real numbers only.

This Character Table for the D_33d point group was created by Gernot Katzer.

For other groups and some explanations, see the Main Page.

	D_31d
	D_32d
C₃₃ C_33v C_33h D₃₃ D_33h	D_33d
	D_34d
	D_35d

Character table for the D33d point group

Character table for the D_33d point group